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新疆北部典型区域松针中有机氯农药的含量及分布

Concentrations and distribution of organochlorine pesticides in pine needles of typical regions in Northern Xinjiang.

作者信息

Lei Xiaoning, Ran Dan, Lu Jianjiang, Du Zhijian, Liu Zilong

机构信息

Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi, 832003, Xingjiang, China.

出版信息

Environ Sci Pollut Res Int. 2015 Feb;22(3):1705-12. doi: 10.1007/s11356-013-1846-z. Epub 2013 Jun 6.

Abstract

The residues of organochlorine pesticides (OCPs) in 29 pine needle samples of typical regions (including Shihezi, Beitun, and Kanas) in Northern Xinjiang was determined with a gas chromatograph equipped with an electron capture detector. Total OCPs concentrations in pine needles ranged from 2.94 to 186 ng/g dry weight, with a mean concentration of 39.63 ng/g. The results indicated that Beitun was the most polluted region while Kanas was the least polluted one. Hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) were the predominant species in samples. Analysis of the sources of contamination showed that HCHs in the needles were derived from an old mixed source of technical HCHs or lindane. For DDTs, it was suspected to have recent application at some sites, which were derived mainly from a mixture of technical DDTs and dicofol containing DDT impurities. Categorical principal component analysis was performed in finding out more about the degradation behavior of DDTs and HCHs, which was identical with the results of source analysis.

摘要

采用配备电子捕获检测器的气相色谱仪测定了新疆北部典型地区(包括石河子、北屯和喀纳斯)29个松针样品中有机氯农药(OCPs)的残留量。松针中总OCPs浓度范围为2.94至186 ng/g干重,平均浓度为39.63 ng/g。结果表明,北屯是污染最严重的地区,而喀纳斯是污染最轻的地区。六氯环己烷(HCHs)和二氯二苯三氯乙烷(DDTs)是样品中的主要种类。污染源分析表明,松针中的HCHs来源于工业六六六或林丹的旧混合源。对于DDTs,怀疑在某些地点有近期使用情况,其主要来源于工业DDTs和含有DDT杂质的三氯杀螨醇的混合物。进行了分类主成分分析以进一步了解DDTs和HCHs的降解行为,其结果与源分析结果一致。

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