Pd(II) 催化下温和条件下肟酸与苯基金三氟硼酸钾的脱羧交叉偶联反应。
Pd(II)-catalyzed decarboxylative cross-coupling of oxamic acids with potassium phenyltrifluoroborates under mild conditions.
机构信息
Department of Chemistry and Chemical Biology, Indiana University Purdue University Indianapolis (IUPUI), 402 N. Blackford St. Indianapolis, IN 46202, USA.
出版信息
Chem Commun (Camb). 2011 Jun 21;47(23):6587-9. doi: 10.1039/c1cc11635e. Epub 2011 May 3.
PMID:21541423
Abstract
A novel Pd-catalyzed decarboxylative cross-coupling of oxamic acids with potassium phenyltrifluoroborates has been realized under mild reaction conditions. This method provides an efficient access to N-mono- or N,N-disubstituted benzamides and benzoates.
摘要
一种新型的钯催化的氧肟酸与苯基金三氟硼酸钾的脱羧交叉偶联反应在温和的反应条件下实现了。该方法为 N-单取代或 N,N-二取代的苯甲酰胺和苯甲酸酯提供了一种有效的合成途径。
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