室温下 Pd(II)催化的芳基三氟硼酸钾与α-氧代羧酸的脱羧交叉偶联反应。
Pd(II)-catalyzed decarboxylative cross-coupling of potassium aryltrifluoroborates with α-oxocarboxylic acids at room temperature.
机构信息
Department of Chemistry and Chemical Biology, Indiana University Purdue University Indianapolis (IUPUI), Indianapolis, Indiana 46202, USA.
出版信息
Org Lett. 2011 Apr 15;13(8):2062-4. doi: 10.1021/ol200459v. Epub 2011 Mar 10.
PMID:21391715
Abstract
A novel Pd-catalyzed decarboxylative cross-coupling of potassium aryltrifluoroborates with α-oxocarboxylic acids is performed at room temperature. This reaction provides an efficient access to aryl ketones under mild conditions.
摘要
一种新型的 Pd 催化的芳基三氟硼酸钾与α-氧代羧酸的脱羧交叉偶联反应在室温下进行。该反应在温和条件下提供了一种有效的方法来制备芳基酮。
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