室温下钯催化的乙酰苯胺与α-氧代羧酸的脱羧邻酰化反应。
Room temperature palladium-catalyzed decarboxylative ortho-acylation of acetanilides with alpha-oxocarboxylic acids.
机构信息
Department of Chemistry and Chemical Biology, Indiana University Purdue University Indianapolis, Indianapolis, Indiana 46202, USA.
出版信息
J Am Chem Soc. 2010 Sep 1;132(34):11898-9. doi: 10.1021/ja105245f.
PMID:20698536
Abstract
A novel Pd-catalyzed decarboxylative ortho-acylation of acetanilides with alpha-oxocarboxylic acids is realized at room temperature. This reaction provides efficient access to o-acyl acetanilides under mild conditions.
摘要
一种新型的 Pd 催化的室温下乙酰苯胺与α-氧代羧酸的脱羧邻位酰化反应被实现。该反应在温和条件下为邻酰基乙酰苯胺提供了有效的合成途径。
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