镍氮杂环卡宾-吡啶配合物，对二氧化碳在水中的电化学还原具有选择性。
Nickel N-heterocyclic carbene-pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water.
机构信息
Department of Chemistry, University of California, Berkeley, California, 94720, USA.
出版信息
Chem Commun (Camb). 2011 Jun 21;47(23):6578-80. doi: 10.1039/c1cc10449g. Epub 2011 May 10.
PMID:21556400
Abstract
We report a homologous series of nickel(II) complexes supported by N-heterocyclic carbene-pyridine ((R)bimpy, R = Me, Et, Pr) ligands that exhibit high selectivity for reducing carbon dioxide over water under electrocatalytic conditions.
摘要
我们报道了一系列由 N-杂环卡宾-吡啶（(R)bimpy，R = Me，Et，Pr）配体支持的镍(II)配合物，它们在电催化条件下对还原二氧化碳具有很高的选择性，超过了水。
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