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基于苯并咪唑的三脚架受体对碘化物的显色和荧光识别。

Chromogenic and fluorescent recognition of iodide with a benzimidazole-based tripodal receptor.

机构信息

Department of Chemistry, Yonsei University, Wonju, Gangwon 220-710, Korea.

出版信息

Org Lett. 2011 Jun 17;13(12):3024-7. doi: 10.1021/ol2008846. Epub 2011 May 16.

DOI:10.1021/ol2008846
PMID:21574613
Abstract

A novel 1,3,5-substituted triethylbenzene derivative with a 2-aminobenzimidazole moiety as a binding and signaling subunit was synthesized. The sensor was tested in a buffered CH(3)CN/H(2)O (99:1, v/v) solution and found to be selective for iodide as demonstrated by the photophysical properties obtained through UV-vis absorption and fluorescence spectroscopy analyses.

摘要

合成了一种新型的含 2-氨基苯并咪唑部分的 1,3,5-三取代三乙基苯衍生物,作为结合和信号亚单位。通过紫外-可见吸收和荧光光谱分析得到的光物理性质表明,该传感器在缓冲的 CH(3)CN/H(2)O(99:1,v/v)溶液中对碘化物具有选择性。

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