顺式-双[(1-金刚烷基甲基)胺-κN]-二氯铂(II) N,N-二甲基甲酰胺溶剂合物
cis-Bis[(1-adamantylmeth-yl)amine-κN]-dichloridoplatinum(II) N,N-dimethyl-formamide solvate.
作者信息
Rochon Fernande D, Tessier Christian
机构信息
Département de Chimie, Université du Québec à Montréal, CP 8888, Succ. Centre-ville, Montréal, Québec, Canada H3 C 3P8.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1297-8. doi: 10.1107/S1600536809037982.
The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo-[3.3.1]non-1-ylmeth-yl)-amine-κN]platinum(II) N,N-dimethyl-formamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethyl-formamide solvent mol-ecules. Each Pt(II) center is coordinated by the amine groups of two (1-adamantylmeth-yl)amine ligands and two Cl atoms in a cis-square-planar arrangement. The Pt(II) centers lie slightly outside [0.031 (4) and 0.038 (4) Å] the coordination planes. The N-Pt-N and Cl-Pt-Cl angles [92.1 (4)-92.30 (11)°] are slightly more open than the N-Pt-Cl angles [87.3 (3)-88.3 (3)°]. N-H⋯O and N-H⋯Cl inter-molecular hydrogen bonds are observed, forming two discrete pairs of complexes and solvent mol-ecules.
标题化合物{系统名称：顺式二氯双[(3,7-二甲基双环-[3.3.1]壬-1-基甲基)-胺-κN]铂(II)}，[PtCl₂(C₁₁H₁₉N)₂]·C₃H₇NO的不对称单元由两个结构相似的铂配合物和两个二甲基甲酰胺溶剂分子组成。每个Pt(II)中心由两个(1-金刚烷基甲基)胺配体的胺基和两个Cl原子以顺式平面正方形排列配位。Pt(II)中心略微位于配位平面之外[0.031 (4)和0.038 (4) Å]。N-Pt-N和Cl-Pt-Cl角[92.1 (4)-92.30 (11)°]比N-Pt-Cl角[87.3 (3)-88.3 (3)°]稍大。观察到分子间存在N-H⋯O和N-H⋯Cl氢键，形成了两对离散的配合物和溶剂分子。
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