二丁基[N-(5-氯-2-氧化苄叉基)-L-异亮氨酸根合-κO,N,O']锡(IV)
Dibut-yl[N-(5-chloro-2-oxidobenzyl-idene)-l-isoleucinato-κO,N,O']tin(IV).
作者信息
Yang Hong-Jun, Dang Yan-Qiu
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1304. doi: 10.1107/S1600536809039245.
Abstract
The Sn(IV) atom of the title compound, [Sn(C(4)H(9))(2)(C(13)H(14)ClNO(3))], adopts a distorted SnNC(2)O(2) trigonal-bipyramidal geometry with a mean Sn-C distance of 2.105 Å and with Sn-O = 2.107 Å, and forms five- and six-membered chelate rings with the tridentate ligand. One butyl group is disordered over two positions with site occupancies of 0.65 (1):0.35 (1).
摘要
标题化合物[Sn(C₄H₉)₂(C₁₃H₁₄ClNO₃)]中的Sn(IV)原子采用扭曲的SnNC₂O₂三角双锥几何构型，平均Sn-C键长为2.105 Å，Sn-O键长为2.107 Å，并与三齿配体形成五元环和六元螯合环。一个丁基在两个位置上无序分布，占位比为0.65(1):0.35(1)。
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本文引用的文献
1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
One-step preparation, structural assignment, and X-ray study of 2,2-di-n-butyl- and 2,2-diphenyl-6-aza-1,3-dioxa-2-stannabenzocyclononen-4-ones derived from amino acids.由氨基酸衍生的2,2-二正丁基-和2,2-二苯基-6-氮杂-1,3-二氧杂-2-锡杂苯并环壬-4-酮的一步制备、结构确定及X射线研究
Chemistry. 2003 May 23;9(10):2291-306. doi: 10.1002/chem.200204260.
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