Paşaoğlu Hümeyra, Kaştaş Gökhan, Yeşilel Okan Z, Yıldırım M Hakkı
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):m1337-8. doi: 10.1107/S1600536809040264.
In the title mononuclear copper(II) compound, [Cu(C(2)O(4))(C(4)H(12)N(2)O)], the Cu(II) ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxy-ethyl)ethyl-enediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of ox ligand form the basal plane, while the O atom of the ethanol group of the HydEt-en ligand is located in the axial position. The complex mol-ecules participate in a supra-molecular assembly through N-H⋯O and O-H⋯O hydrogen bonds between HydEt-en and ox ligands.
在标题单核铜(II)化合物[Cu(C₂O₄)(C₄H₁₂N₂O)]中,Cu(II)离子具有略微扭曲的四方锥几何构型,带有一个三齿的N-(2-羟乙基)乙二胺(HydEt-en)和一个双齿的草酸根(ox)配体。HydEt-en配体的N原子和ox配体的O原子形成基面,而HydEt-en配体乙醇基团的O原子位于轴向位置。配合物分子通过HydEt-en和ox配体之间的N-H⋯O和O-H⋯O氢键参与超分子组装。