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草酸铜(II)[N-(2-羟乙基)乙二胺]

[N-(2-Hydroxy-ethyl)ethyl-enediamine]oxalatocopper(II).

作者信息

Paşaoğlu Hümeyra, Kaştaş Gökhan, Yeşilel Okan Z, Yıldırım M Hakkı

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):m1337-8. doi: 10.1107/S1600536809040264.

Abstract

In the title mononuclear copper(II) compound, [Cu(C(2)O(4))(C(4)H(12)N(2)O)], the Cu(II) ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxy-ethyl)ethyl-enediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of ox ligand form the basal plane, while the O atom of the ethanol group of the HydEt-en ligand is located in the axial position. The complex mol-ecules participate in a supra-molecular assembly through N-H⋯O and O-H⋯O hydrogen bonds between HydEt-en and ox ligands.

摘要

在标题单核铜(II)化合物[Cu(C₂O₄)(C₄H₁₂N₂O)]中,Cu(II)离子具有略微扭曲的四方锥几何构型,带有一个三齿的N-(2-羟乙基)乙二胺(HydEt-en)和一个双齿的草酸根(ox)配体。HydEt-en配体的N原子和ox配体的O原子形成基面,而HydEt-en配体乙醇基团的O原子位于轴向位置。配合物分子通过HydEt-en和ox配体之间的N-H⋯O和O-H⋯O氢键参与超分子组装。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/adfb/2970959/d039e343cb5c/e-65-m1337-fig1.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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