Robinson Tony V, Taylor Dennis K, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):o3129. doi: 10.1107/S160053680904848X.
The title compound, C(13)H(16)O, comprises two fused five-membered rings. Each ring has an envelope conformation, with the ether O atom in the furan-ose ring, and the CMe(2) atom in the acetonide ring as the flap atoms. In the crystal, centrosymmetrically related mol-ecules associate via hydr-oxy-ether O-H⋯O hydrogen bonds and the resulting dimers are linked into a supra-molecular chain with a flattened topology via C-H⋯O(hydr-oxy) contacts, and aligned in the a-axis direction.
标题化合物C(13)H(16)O由两个稠合的五元环组成。每个环都具有信封式构象,呋喃糖环中的醚O原子和缩酮环中的CMe(2)原子作为瓣原子。在晶体中,中心对称相关的分子通过羟基醚O-H⋯O氢键缔合,所得二聚体通过C-H⋯O(羟基)接触连接成具有扁平拓扑结构的超分子链,并沿a轴方向排列。