• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2,4-二溴-6-{（E）-[（R）-1-苯基-乙基]亚氨基-甲基}苯酚

2,4-Dibromo-6-{(E)-[(R)-1-phenyl-ethyl]imino-meth-yl}phenol.

作者信息

Xia Dong-Guo, Ye Ya-Fen, Lei Ke-Wei

机构信息

State Key Laboratory Base of Novel Functional Materials and Preparation Science Institute of solid Materials Chemistry, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):o3168. doi: 10.1107/S1600536809044638.

DOI:10.1107/S1600536809044638
PMID:21578884
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2972087/
Abstract

In the title Schiff base, C(15)H(13)Br(2)NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)°. The N=C bond length of 1.263 (6) Å is shorter than of the N-C bond [1.476 (5) Å], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the two mol-ecules are centrosymmetrically related. The mol-ecular structure is stabilized by intra-molecular O-H⋯N hydrogen bonds.

摘要

在席夫碱C(15)H(13)Br(2)NO的标题中，苯环和苯基环形成的二面角为75.18 (13)°。N=C键长为1.263 (6) Å，比N-C键长[1.476 (5) Å]短，表明存在双键。在晶体中，存在一些假对称性。这是因为两个分子中的大多数是中心对称相关的。分子结构通过分子内O-H⋯N氢键得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b5e/2972087/dfc4c7d6c638/e-65-o3168-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b5e/2972087/dfc4c7d6c638/e-65-o3168-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b5e/2972087/dfc4c7d6c638/e-65-o3168-fig1.jpg

相似文献

1
2,4-Dibromo-6-{(E)-[(R)-1-phenyl-ethyl]imino-meth-yl}phenol.2,4-二溴-6-{（E）-[（R）-1-苯基-乙基]亚氨基-甲基}苯酚
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):o3168. doi: 10.1107/S1600536809044638.
2
Crystal structure of (E)-5-di-ethyl-amino-2-({[4-(di-methyl-amino)-phen-yl]imino}-meth-yl)phenol.（E）-5-二乙氨基-2-（{[4-（二甲基氨基）苯基]亚氨基}-甲基）苯酚的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jun 24;71(Pt 7):o503. doi: 10.1107/S2056989015011779. eCollection 2015 Jul 1.
3
2-[(E)-(4-Fluoro-benzyl-imino)-meth-yl]-4-methyl-phenol.2-[(E)-(4-氟-苄基亚氨基)-甲基]-4-甲基苯酚
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2149. doi: 10.1107/S1600536812027018. Epub 2012 Jun 20.
4
A chiral photochromic Schiff base: (R)-4-meth-oxy-2-[(1-phenyl-ethyl)imino-meth-yl]phenol.一种手性光致变色席夫碱：(R)-4-甲氧基-2-[(1-苯基-乙基)亚氨基甲基]苯酚。
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 9;65(Pt 10):o2381. doi: 10.1107/S1600536809035557.
5
Crystal structure of (E)-2-{[(4-anilinophen-yl)imino]-meth-yl}phenol.（E）-2-{[（4-苯胺基苯基）亚氨基]甲基}苯酚的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 1;71(Pt 1):28-30. doi: 10.1107/S2056989014026309.
6
2-Methyl-6-[2-(trifluoro-meth-yl)phenyl-imino-meth-yl]phenol.2-甲基-6-[2-(三氟甲基)苯基亚氨基甲基]苯酚
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 31;65(Pt 11):o2949. doi: 10.1107/S1600536809044560.
7
2-[(E)-(4-Fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenol.2-[(E)-(4-氟苄基)亚氨基甲基]-6-甲氧基苯酚
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2401. doi: 10.1107/S1600536812027419. Epub 2012 Jul 10.
8
2-{(E)-[(3-Iodo-4-methyl-phen-yl)imino]-meth-yl}-4-(trifluoro-meth-oxy)phenol.2-{(E)-[(3-碘-4-甲基苯基)亚氨基]甲基}-4-(三氟甲氧基)苯酚
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2148. doi: 10.1107/S1600536812026876. Epub 2012 Jun 20.
9
6,6'-Dimeth-oxy-2,2'-[(E,E')-(2,4,6-trimethyl-1,3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate.6,6'-二甲氧基-2,2'-[(E,E')-(2,4,6-三甲基-1,3-亚苯基)双(亚氨甲基亚基)]二苯酚氯仿单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o1176. doi: 10.1107/S1600536812011531. Epub 2012 Mar 24.
10
4-Bromo-2-({4-[(hy-droxy-imino)-meth-yl]phen-yl}imino-meth-yl)phenol.4-溴-2-({4-[(羟基亚氨基)甲基]苯基}亚氨基甲基)苯酚
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 14;66(Pt 8):o2014. doi: 10.1107/S160053681002698X.

引用本文的文献

1
4-Fluoro-N-[(E)-3,4,5-tri-meth-oxy-benzyl-idene]aniline.4-氟-N-[(E)-3,4,5-三甲氧基亚苄基]苯胺
Acta Crystallogr Sect E Struct Rep Online. 2013 Jul 10;69(Pt 8):o1234. doi: 10.1107/S1600536813017741. eCollection 2013.
2
N-[4-(Di-methyl-amino)-benzyl-idene]-4-methyl-aniline.N-[4-(二甲基氨基)-亚苄基]-4-甲基苯胺
Acta Crystallogr Sect E Struct Rep Online. 2013 May 18;69(Pt 6):o905. doi: 10.1107/S160053681301249X. Print 2013 Jun 1.
3
N-[(E)-4-Fluoro-benzyl-idene]-3,4-di-methyl-aniline.N-[(E)-4-氟-亚苄基]-3,4-二甲基苯胺

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2415. doi: 10.1107/S1600536812030474. Epub 2012 Jul 10.
4
2-[(E)-(4-Fluoro-benzyl-imino)-meth-yl]-4-methyl-phenol.2-[(E)-(4-氟-苄基亚氨基)-甲基]-4-甲基苯酚
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2149. doi: 10.1107/S1600536812027018. Epub 2012 Jun 20.