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N-[4-(二甲基氨基)-亚苄基]-4-甲基苯胺

N-[4-(Di-methyl-amino)-benzyl-idene]-4-methyl-aniline.

作者信息

Balachandar R K, Kalainathan S, Eappen Shibu M, Podder Jiban

机构信息

Centre for Crystal Growth, School of Advanced Sciences, VIT University, Vellore 632 014, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 May 18;69(Pt 6):o905. doi: 10.1107/S160053681301249X. Print 2013 Jun 1.

DOI:10.1107/S160053681301249X
PMID:23795079
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3685060/
Abstract

The mol-ecules of the title compound, C16H18N2, exists in a trans conformation with respect to the C=N bond [1.270 (3) Å]. The least-squares plane of the di-methyl-amino group makes a dihedral angle of 1.3 (2)° with the ring to which it is attached. The dihedral angle between the two aromatic rings is 11.70 (2)°. The crystal structure features weak C-H⋯π inter-actions.

摘要

标题化合物C₁₆H₁₈N₂的分子相对于C=N键[1.270 (3) Å]呈反式构象。二甲基氨基的最小二乘平面与其所连接的环形成1.3 (2)°的二面角。两个芳环之间的二面角为11.70 (2)°。晶体结构具有弱的C-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/951e/3685060/94f045d4f20d/e-69-0o905-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/951e/3685060/c9df9d4b0d91/e-69-0o905-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/951e/3685060/94f045d4f20d/e-69-0o905-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/951e/3685060/c9df9d4b0d91/e-69-0o905-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/951e/3685060/94f045d4f20d/e-69-0o905-fig2.jpg

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