双[μ-1,2-双-(1,2,4-三唑-4-基)乙烷]双[二碘锌(II)]。
Bis[μ-1,2-bis-(1,2,4-triazol-4-yl)ethane]bis-[diiodidozinc(II)].
作者信息
Feng Yunfei, Liang Na, Li Baolong, Li Haiyan
机构信息
College of Chemistry and Chemical Engineering and Material Science, The Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou University, Suzhou 215123, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 24;66(Pt 5):m560. doi: 10.1107/S1600536810014121.
In the title dinuclear complex, [Zn(2)I(4)(C(6)H(8)N(6))(2)], two Zn(II )atoms are bridged by two 1,2-bis-(1,2,4-triazol-4-yl)ethane (btre) ligands, forming a centrosymmetric metallacycle. The coordination geometry of the Zn(II) ion is distorted tetra-hedral with the coordination sphere formed by two N atoms from the triazole rings of two symmetry-related btre ligands and two iodide ligands.
在双核配合物[Zn₂I₄(C₆H₈N₆)₂]中，两个锌（II）原子由两个1,2-双（1,2,4-三唑-4-基）乙烷（btre）配体桥联，形成一个中心对称的金属环。锌（II）离子的配位几何构型为扭曲的四面体，其配位球由来自两个对称相关的btre配体的三唑环的两个氮原子和两个碘化物配体形成。
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