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A dimeric zinc(II) complex: bis-[μ-1,2-bis-(1,2,4-triazol-4-yl)ethane-κN:N]bis-[dinitritozinc(II)].

作者信息

Zhang Rongxian, Chen Qiuyun, Gao Jing, Wu Xiangyang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 4;66(Pt 10):m1208. doi: 10.1107/S1600536810034203.

Abstract

The coordination geometry of the Zn(II) atom in the title complex, [Zn(2)(NO(2))(4)(C(6)H(8)N(6))(2)], is distorted octa-hedral, in which the Zn(II) atom is coordinated by two N atoms from the triazole rings of two symmetry-related 1,2-bis-(1,2,4-triazol-4-yl)ethane ligands and four O atoms from two nitrite ligands. Two Zn(II) atoms are bridged by two organic ligands, forming a centrosymmetric dimer. Weak C-H⋯N and C-H⋯O hydrogen bonds play an important role in the inter-molecular packing.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e1/2983239/23f10324034b/e-66-m1208-fig1.jpg

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