Zhang Rongxian, Chen Qiuyun, Gao Jing, Wu Xiangyang
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 4;66(Pt 10):m1208. doi: 10.1107/S1600536810034203.
The coordination geometry of the Zn(II) atom in the title complex, [Zn(2)(NO(2))(4)(C(6)H(8)N(6))(2)], is distorted octa-hedral, in which the Zn(II) atom is coordinated by two N atoms from the triazole rings of two symmetry-related 1,2-bis-(1,2,4-triazol-4-yl)ethane ligands and four O atoms from two nitrite ligands. Two Zn(II) atoms are bridged by two organic ligands, forming a centrosymmetric dimer. Weak C-H⋯N and C-H⋯O hydrogen bonds play an important role in the inter-molecular packing.
在标题配合物[Zn(2)(NO(2))(4)(C(6)H(8)N(6))(2)]中,Zn(II)原子的配位几何形状为扭曲的八面体,其中Zn(II)原子由来自两个对称相关的1,2-双-(1,2,4-三唑-4-基)乙烷配体的三唑环的两个N原子和来自两个亚硝酸根配体的四个O原子配位。两个Zn(II)原子由两个有机配体桥联,形成一个中心对称的二聚体。弱的C-H⋯N和C-H⋯O氢键在分子间堆积中起重要作用。