Wang Sulian, Lu Liping, Feng Sisi, Zhu Miaoli
Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 May 8;66(Pt 6):m632. doi: 10.1107/S1600536810016442.
In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the V(10)O(28) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa-hedral geometry. Eight terminal O atoms are bonded to V(V) atoms with double bonds and the others act as bridging atoms. In the crystal structure, a network of N-H⋯O and O-H⋯O hydrogen bonds helps to establish the packing.
在标题化合物（C₂H₈N）₆[V₁₀O₂₈]·H₂O中，[V₁₀O₂₈]⁶⁻多金属酸根阴离子具有晶体学镜面对称性，六个V原子和十二个O原子位于镜面上。每个V（V）原子采用扭曲的八面体几何构型。八个末端O原子通过双键与V（V）原子键合，其他O原子则作为桥连原子。在晶体结构中，N-H⋯O和O-H⋯O氢键网络有助于形成堆积。
