Li Yu-Feng, Wang Lin-Tong, Jian Fang-Fang
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 13;66(Pt 2):m141. doi: 10.1107/S1600536809055640.
In the title compound, Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)·2H(2)O, the Cu(II) ion is bonded to two N,N'-bidentate 2,2'-bipyridyl ligands and one O-monodentate 2,2-dichloro-acetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O-H⋯O and O-H⋯Cl hydrogen bonds.
在标题化合物Cu(C₂HCl₂O₂)(C₁₀H₈N₂)₂·2H₂O中,Cu(II)离子以扭曲的CuON₄三角双锥几何构型与两个N,N'-双齿2,2'-联吡啶配体和一个O-单齿二氯乙酸根阴离子键合,其中O原子占据一个赤道位置。在晶体中,各组分通过O-H⋯O和O-H⋯Cl氢键相连。