（μ-乙酸根）{μ-1,3-双[2-（2-氧化苯亚甲基氨基）乙基]-2-（2-氧化苯基）-1,3-咪唑啉}二锌（II）乙醇溶剂合物二水合物
(μ-Acetato){μ-1,3-bis[2-(2-oxidobenzylideneamino)ethyl]-2-(2-oxidophenyl)-1,3-imidazolidine}dizinc(II) ethanol disolvate dihydrate.
作者信息
Lu Xiao-Ping, Zhu Miao-Li, Lu Li-Ping
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):m729-30. doi: 10.1107/S1600536809020716.
Abstract
In the title binuclear compound, [Zn(2)(C(27)H(27)N(4)O(3))(C(2)H(3)O(2))]·2CH(3)CH(2)OH·2H(2)O, both Zn cations adopt distorted ZnO(3)N(2) trigonal-bipyramidal geometries with one N atom in a axial site and one N atom in an equatorial site, arising from coordination by the N,N,N,N,O,O,O-hepta-dentate ligand and a bridging acetate ion. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the component units into a three-dimensional network. Two short C-H⋯O contacts are also seen.
摘要
在标题双核化合物[Zn₂(C₂₇H₂₇N₄O₃)(C₂H₃O₂)]·2CH₃CH₂OH·2H₂O中，两个锌阳离子均采用扭曲的ZnO₃N₂三角双锥几何构型，一个氮原子位于轴向位置，一个氮原子位于赤道位置，这是由N,N,N,N,O,O,O-七齿配体和一个桥连乙酸根离子配位所致。在晶体中，分子间的O-H⋯O氢键将各组成单元连接成三维网络。还观察到两个短的C-H⋯O接触。
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