{2-乙氧基-6-[2-(哌啶-1-基)乙基亚氨基甲基]苯酚根}二碘合锌(II)
{2-Eth-oxy-6-[2-(piperidinium-1-yl)ethyl-imino-meth-yl]phenolato}diiodidozinc(II).
作者信息
Li Jing-Yan
机构信息
Department of Chemistry, Baicheng Normal College, Baicheng 137000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):m1611. doi: 10.1107/S1600536809048491.
Abstract
The title Schiff base complex, [ZnI(2)(C(16)H(24)N(2)O(2))], is a mononuclear zinc(II) compound. The Zn atom is four-coordinated in a distorted tetra-hedral geometry by one phenolate O atom and one imine N atom of the Schiff base ligand and by two iodide ions. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the a axis.
摘要
席夫碱配合物[ZnI₂(C₁₆H₂₄N₂O₂)]的标题化合物是一种单核锌(II)化合物。锌原子通过席夫碱配体的一个酚氧原子、一个亚胺氮原子以及两个碘离子以扭曲的四面体几何构型进行四配位。在晶体结构中，分子通过分子间的N-H⋯O氢键相连，形成沿a轴延伸的链。
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