{4,4'-二甲氧基-2,2'-[2,2-二甲基丙烷-1,3-二亚基双(亚氨基次甲基)]二酚根合}镍(II)
{4,4'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}nickel(II).
作者信息
Montazerozohori Morteza, Habibi Mohammad Hossein, Mokhtari Reza, Yamane Yuki, Suzuki Takayoshi
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):m703. doi: 10.1107/S1600536809019965.
Abstract
In the title complex, [Ni(C(21)H(24)N(2)O(4))], the Ni(II) ion has a slightly distorted square-planar geometry, coordinated by the two N and two O atoms of a new tetra-dentate Schiff base ligand. The dihedral angle between the planes of the two NiNC(3)O chelate rings is 14.37 (12)°.
摘要
在标题配合物[Ni(C₂₁H₂₄N₂O₄)]中，Ni(II)离子具有轻微扭曲的平面正方形几何构型，由一种新型四齿席夫碱配体的两个N原子和两个O原子配位。两个NiNC₃O螯合环平面之间的二面角为14.37 (12)°。
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