Zhou Fangxia
Department of Chemistry , Jining University, Shandong 273155, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 9;66(Pt 1):m35. doi: 10.1107/S1600536809052015.
The structure of the polymeric title complex, {[Cd(C(6)H(6)N(2)O(6))(H(2)O)(3)]·2H(2)O}(n), consists of chains running parallel to [01] in which the oxamidato ligand, deprotonated only at the carboxyl-ate groups, acts as a bridging bis-monodentate ligand. The Cd atom and the O atom of a coordinated water mol-ecule are located on a twofold axis. The coordination geometry around the Cd atom is distorted trigonal-pyramidal. In the crystal structure, neighbouring chains are linked into a three-dimensional network by inter-chain O-H⋯O and N-H⋯O hydrogen bonds.
聚合物标题配合物{[Cd(C₆H₆N₂O₆)(H₂O)₃]·2H₂O}ₙ的结构由平行于[01]方向的链组成,其中草酰胺酸根配体仅在羧酸根基团处去质子化,作为桥联双单齿配体。镉原子和一个配位水分子的氧原子位于二重轴上。镉原子周围的配位几何形状为扭曲的三角锥。在晶体结构中,相邻的链通过链间O—H⋯O和N—H⋯O氢键连接成三维网络。