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一种一维之字形配位聚合物：链状聚[[[三水合镉（II）]-[μ-2,2'-（5-甲基-1,3-苯二氧基）二乙酸根-κO,O':O'',O''']]]一水合物

A one-dimensional zigzag coordination polymer: catena-poly[[[triaqua-cadmium(II)]-[μ-2,2'-(5-methyl-1,3-phenyl-enedi-oxy)diacetato-κO,O':O'',O''']] monohydrate].

作者信息

Lin Ying, Wei Yun, Wei Xian-Wen, Zhang Hong-Tao

机构信息

College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Normal University, Wuhu 241000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 4;64(Pt 2):m280-1. doi: 10.1107/S1600536807068031.

DOI:10.1107/S1600536807068031
PMID:21201262
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960183/
Abstract

In the title one-dimensional coordination polymer, {[Cd(C(11)H(10)O(6))(H(2)O)(3)]·H(2)O}(n), the 2,2'-(5-methyl-1,3-phenyl-enedi-oxy)diacetate dianions connect Cd(II) ions in a head-to-tail fashion to generate zigzag chains. The coordination geometry of the Cd atom is distorted penta-gonal bipyramidal. There are O-H⋯O hydrogen bonds between the carboxyl O atoms, the aqua ligands and the uncoordinated water mol-ecules.

摘要

在标题中的一维配位聚合物{[Cd(C₁₁H₁₀O₆)(H₂O)₃]·H₂O}ₙ中，2,2'-（5-甲基-1,3-苯二氧基）二乙酸二价阴离子以头对尾的方式连接Cd(II)离子，形成锯齿链。Cd原子的配位几何形状为扭曲的五角双锥。羧基O原子、水配体和未配位的水分子之间存在O-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/67d5/2960183/8e6b0b7e8a2b/e-64-0m280-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/67d5/2960183/a2a68f501d7f/e-64-0m280-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/67d5/2960183/8e6b0b7e8a2b/e-64-0m280-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/67d5/2960183/a2a68f501d7f/e-64-0m280-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/67d5/2960183/8e6b0b7e8a2b/e-64-0m280-fig2.jpg

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A one-dimensional zigzag coordination polymer: catena-poly[[[triaqua-cadmium(II)]-[μ-2,2'-(5-methyl-1,3-phenyl-enedi-oxy)diacetato-κO,O':O'',O''']] monohydrate].一种一维之字形配位聚合物：链状聚[[[三水合镉（II）]-[μ-2,2'-（5-甲基-1,3-苯二氧基）二乙酸根-κO,O':O'',O''']]]一水合物
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catena-Poly[(diaqua-cadmium)-μ-4,4'-[sulfonyl-bis-(1,4-phenyl-ene-oxy)]-di-acet-ato-κO,O':O'',O'''].链状聚[（二水合镉）-μ-4,4'-[磺酰基双（1,4-亚苯基氧基）]二乙酸根合-κO，O'：O''，O''']
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catena-Poly[[[diaqua-cadmium]-μ-2,2'-(1,2-phenyl-enedi-oxy)diacetato] mono-hydrate].链状聚[[[二水合镉]-μ-2,2'-(1,2-苯二氧基)二乙酸根]一水合物]
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catena-Poly[[(triaqua-cadmium)-μ-1,4-phenyl-enediacetato-κO,O':O'',O'''] dihydrate].链状聚[[(三水合镉)-μ-1,4-苯二甲酸根合-κO,O':O'',O''']二水合物]
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catena-Poly[[diaqua-cobalt(II)]-μ-4,4'-[1,4-phenyl-enebis(-oxy)]dibutano-ato-κO,O':O'',O'''].链状聚[[二水合钴（II）]-μ-4,4'-[1,4-亚苯基双（-氧基）]二丁酸根合-κO，O'：O''，O''']
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本文引用的文献

1
Functional porous coordination polymers.功能性多孔配位聚合物
Angew Chem Int Ed Engl. 2004 Apr 26;43(18):2334-75. doi: 10.1002/anie.200300610.
2
From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.从分子到晶体工程：网络固体中的超分子异构现象和多晶型现象
Chem Rev. 2001 Jun;101(6):1629-58. doi: 10.1021/cr9900432.