二氯（1,10-菲咯啉-κN,N'）钯（II）
Dichlorido(1,10-phenanthroline-κN,N')palladium(II).
作者信息
Ha Kwang
机构信息
School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m38. doi: 10.1107/S1600536809052313.
In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol-ecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd⋯Pd distance of 4.8340 (9) Å. In the column, π-π inter-actions between adjacent six-membered rings are present, the shortest centroid-centroid distance being 3.680 (4) Å. A weak C-H⋯Cl inter-action is observed between the columns.
在标题配合物[PdCl₂(C₁₂H₈N₂)]中，Pd²⁺离子在略微扭曲的平面正方形环境中通过螯合的1,10 - 菲咯啉配体的两个N原子和两个氯离子进行四配位。这些近乎平面的分子与最小二乘平面的最大偏差为0.120 (3) Å，它们沿着c轴堆积成列，Pd⋯Pd距离为4.8340 (9) Å。在列中，相邻六元环之间存在π - π相互作用，最短的质心 - 质心距离为3.680 (4) Å。在列之间观察到弱的C - H⋯Cl相互作用。
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