二溴（1,10-菲咯啉-κN,N'）钯（II）
Dibromido(1,10-phenanthroline-κN,N')palladium(II).
作者信息
Ha Kwang
机构信息
School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):m7. doi: 10.1107/S160053680905168X.
In the title complex, [PdBr(2)(C(12)H(8)N(2))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two bromide ions. The complex displays numerous inter-molecular π-π inter-actions between adjacent six-membered rings, the shortest centroid-centroid distance being 3.680 (4) Å. The nearly planar [maximum deviation 0.143 (2) Å] mol-ecules stack in columns parallel to (101) with a Pd⋯Pd distance of 4.8466 (9) Å.
在标题配合物[PdBr₂(C₁₂H₈N₂)]中，Pd(II)离子在略微扭曲的平面正方形环境中由螯合的1,10 - 菲咯啉配体的两个N原子和两个溴离子进行四配位。该配合物在相邻的六元环之间展现出大量分子间π - π相互作用，最短的质心 - 质心距离为3.680 (4) Å。近乎平面的[最大偏差0.143 (2) Å]分子沿平行于(101)的方向堆积成列，Pd⋯Pd距离为4.8466 (9) Å。
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