Ha Kwang
School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 16;66(Pt 1):m65. doi: 10.1107/S1600536809053100.
In the title complex, [PtI(2)(C(12)H(8)N(2))], the Pt(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two iodide ions. The nearly planar mol-ecules, with a maximum deviation of 0.170 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pt⋯Pt distance of 4.8510 (6) Å. In the column, π-π inter-actions between adjacent six-membered rings are present, the shortest centroid-centroid distance being 3.703 (5) Å.
在标题配合物[PtI₂(C₁₂H₈N₂)]中，Pt²⁺离子在略微扭曲的平面正方形环境中通过螯合的1,10 - 菲咯啉配体的两个N原子和两个碘离子进行四配位。这些近乎平面的分子，与最小二乘平面的最大偏差为0.170 (3) Å，沿c轴堆叠成列，Pt⋯Pt距离为4.8510 (6) Å。在列中，相邻六元环之间存在π - π相互作用，最短的质心 - 质心距离为3.703 (5) Å。
