双[2-甲氧基-6-(3-吡啶基甲基亚氨基甲基)苯酚根-κN,O]铜(II)
Bis[2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolato-κN,O]copper(II).
作者信息
Chen Xiaodan, Sun Yu, Yao Qingzhao, Zhang Huaihong, Liang Qing
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m39. doi: 10.1107/S1600536809052349.
In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61 (6)° between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component.
在标题配合物[Cu(C₁₄H₁₃N₂O₂)₂]中，Cu(II)离子位于一个晶体学反演中心上。因此，该配合物呈现出平面正方形反式-[CuN₂O₂]配位几何构型，其中Cu(II)离子由两个2-甲氧基-6-(3-吡啶基甲基亚氨基甲基)酚盐（席夫碱）配体配位。席夫碱中的芳基环和吡啶环几乎相互垂直，两个六元环平面之间的二面角为87.61 (6)°。吡啶环使用无序模型进行精修，主要组分的占有率约为70%。
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