二水合双（6-甲氧基-2-{[三（羟甲基）甲基]亚氨基甲基}苯酚根）铜（II）
Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)-meth-yl]-imino-meth-yl}phenolato)-copper(II) dihydrate.
作者信息
Zhang Xiutang, Wei Peihai, Dou Jianmin, Li Bin, Hu Bo
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m151-2. doi: 10.1107/S1600536808043948.
Abstract
In the title compound, [Cu(C(12)H(16)NO(5))(2)]·2H(2)O, the Cu(II) ion adopts a trans-CuN(2)O(4) octa-hedral geometry arising from two N,O,O'-tridentate 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]-imino-meth-yl}phenolate ligands. The Jahn-Teller distortion of the copper centre is unusally small. In the crystal structure, O-H⋯O hydrogen bonds, some of which are bifurcated, link the component species.
摘要
在标题化合物[Cu(C₁₂H₁₆NO₅)₂]·2H₂O中，Cu(II)离子采用反式-CuN₂O₄八面体几何构型，由两个N,O,O'-三齿的6-甲氧基-2-{[三-(羟甲基)甲基]-亚氨基甲基}苯酚盐配体形成。铜中心的 Jahn-Teller 畸变异常小。在晶体结构中，O-H⋯O氢键（其中一些是分叉的）连接各组成部分。
Zotero 插件