Datta Amitabha, Huang Jui-Hsien, Lee Hon Man
National Changhua University of Education, Department of Chemistry, Changhua 50058, Taiwan.
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1497. doi: 10.1107/S1600536808035289.
The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical inter-molecular C-H⋯O hydrogen bonds involving the ether O atoms link the Schiff base mol-ecules into a two-dimensional network parallel to (101).
标题配合物[Cu(C₁₂H₁₆NO₃)₂]具有扭曲的平面正方形配位几何结构，Cu(II)离子位于晶体学反演中心。两个席夫碱配体以反式配位。在晶体结构中，涉及醚氧原子的非经典分子间C—H⋯O氢键将席夫碱分子连接成平行于(101)的二维网络。
