链状聚[[水合-三甲基-锡(IV)]-{[三甲基-锡(IV)]-μ(3)-噻吩-2,5-二羧基-合}]
catena-Poly[[aqua-trimethyl-tin(IV)]-{[trimethyl-tin(IV)]-μ(3)-thio-phene-2,5-dicarboxyl-ato}].
作者信息
Yang Sheng-Xiang, Li Yue-Zhong, Jiang Kun
机构信息
Huai Nan Union University, Huainan, Anhui 232038, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m137. doi: 10.1107/S1600536808043614.
Abstract
In the title compound, Sn(2)(CH(3))(6)(C(6)H(2)O(4)S)(H(2)O), each of the two crystallographically independent Sn atoms exhibits a distorted trigonal-bipyramidal coordination geometry formed by two O and three C atoms. The coordinated water mol-ecule plays an important role in crystal packing consolidation via O-H⋯O hydrogen bonding.
摘要
在标题化合物[Sn₂(CH₃)₆(C₆H₂O₄S)(H₂O)]ₙ中，两个晶体学独立的Sn原子中的每一个都呈现出由两个O原子和三个C原子形成的扭曲三角双锥配位几何构型。配位水分子通过O—H⋯O氢键在晶体堆积巩固中起着重要作用。
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