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链状聚[[二水合二氯锰（II）]-μ-1,1'-双-（1H-1,2,4-三唑-1-基甲基）二茂铁]

catena-Poly[[diaqua-dichlorido-manganese(II)]-μ-1,1'-bis-(1H-1,2,4-triazol-1-ylmeth-yl)ferrocene].

作者信息

Shi Chong-Yu, Zhou Xiao-Li, Wu Bo, Zhu Ni, Weia Zhen-Shu

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 24;66(Pt 1):m96. doi: 10.1107/S1600536809053823.

DOI:10.1107/S1600536809053823
PMID:21579985
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980034/
Abstract

In the title complex, FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2), the Mn(II) atom, located on an inversion center, is octa-hedrally coordinated by two N atoms from two adjacent 1,1'-bis-(1H-1,2,4-triazol-1-ylmeth-yl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water mol-ecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by inter-molecular O-H⋯N hydrogen bonds, which link the chains, forming a two-dimensional layer parallel to (10); O-H⋯Cl inter-actions link the layers, forming a three-dimensional network.

摘要

在标题配合物[FeMn(C₈H₈N₃)₂Cl₂(H₂O)₂]ₙ中，位于对称中心的Mn(II)原子由来自两个相邻的1,1'-双(1H-1,2,4-三唑-1-基甲基)二茂铁(btmf)配体的两个N原子和两个形成赤道平面的Cl原子进行八面体配位，轴向位置由配位水分子的两个O原子占据。btmf配体沿着a轴将相邻的Mn(II)原子连接成之字形链。晶体结构通过分子间O-H⋯N氢键得以稳定，这些氢键连接各链，形成平行于(10)的二维层；O-H⋯Cl相互作用连接各层，形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2cb3/2980034/db896e7a8636/e-66-00m96-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2cb3/2980034/77e814caacae/e-66-00m96-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2cb3/2980034/db896e7a8636/e-66-00m96-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2cb3/2980034/77e814caacae/e-66-00m96-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2cb3/2980034/db896e7a8636/e-66-00m96-fig2.jpg

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本文引用的文献

1
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Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Novel Pb(II), Zn(II), and Cd(II) coordination polymers constructed from ferrocenyl-substituted carboxylate and bipyridine-based ligands.由二茂铁基取代羧酸盐和联吡啶基配体构建的新型铅（II）、锌（II）和镉（II）配位聚合物。
Inorg Chem. 2003 Aug 11;42(16):4995-5004. doi: 10.1021/ic034324a.