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链状聚[[二苯胺二氯化铜(II)]-μ(2)-2,5-双(4-吡啶基)-1,3,4-恶二唑]

catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole].

作者信息

Meng Qinglong, Wu Yiming, Zhang Chi

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 24;66(Pt 1):m97. doi: 10.1107/S1600536809054191.

Abstract

In the title compound, CuCl(2)(C(6)H(7)N)(2)(C(12)H(8)N(4)O), the Cu atom, located on an inversion center, is coordinated by four N atoms from two aniline ligands and two 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands. Two Cl atoms lying above and below the plane formed by these four N atoms inter-act weakly with the Cu atom [Cu-Cl = 2.7870 (7) Å]. The trans 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands act as bridging ligands, linking adjacent Cu atoms and forming a one-dimensional coordination polymer. Two anilines coordinate with each Cu atom as terminal groups. The structure contains two classical N-H⋯Cl and two non-classical C-H⋯Cl hydrogen bonds.

摘要

在标题化合物[CuCl₂(C₆H₇N)₂(C₁₂H₈N₄O)]ₙ中,位于对称中心的Cu原子由来自两个苯胺配体和两个2,5-双(4-吡啶基)-1,3,4-恶二唑配体的四个N原子配位。位于这四个N原子所形成平面上方和下方的两个Cl原子与Cu原子存在弱相互作用[Cu-Cl = 2.7870 (7) Å]。反式2,5-双(4-吡啶基)-1,3,4-恶二唑配体作为桥联配体,连接相邻的Cu原子并形成一维配位聚合物。两个苯胺作为端基与每个Cu原子配位。该结构包含两个经典的N-H⋯Cl和两个非经典的C-H⋯Cl氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0f6/2980127/f3444bf32f87/e-66-00m97-fig1.jpg

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