链状聚[[氯化铜（II）]双（μ-3,3',5,5'-四甲基-4,4'-亚甲基二吡唑）[氯化铜（II）]-二μ-氯]
catena-Poly[[chloridocopper(II)]bis-(μ-3,3',5,5'-tetra-methyl-4,4'-methylene-dipyrazole)[chloridocopper(II)]-di-μ-chlorido].
作者信息
Wang Zhi-Min
机构信息
College of Biology and Environmental Engineering, Zhejiang shuren University, Hangzhou 310015, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 14;64(Pt 4):m561. doi: 10.1107/S1600536808006909.
In the title compound, Cu(2)Cl(4)(C(11)H(16)N(4)), the Cu atom is coordinated by two N atoms of two 3,3',5,5'-tetra-methyl-4,4'-methyl-enedipyrazole (H(2)mbdpz) ligands, two bridging Cl atoms and one terminal Cl atom, forming a square-pyramidal geometry. The bridging Cl atoms and the bridging H(2)mbdpz ligands connect the Cu atoms to build up an extended one-dimensional chain. The chains are further connected through N-H⋯Cl hydrogen bonds to build up a two-dimensional layer in the (011) plane. An inversion centre lies between every pair of adjacent Cu atoms.
在标题化合物[Cu₂Cl₄(C₁₁H₁₆N₄)]ₙ中，铜原子由两个3,3',5,5'-四甲基-4,4'-亚甲基二吡唑（H₂mbdpz）配体的两个氮原子、两个桥连氯原子和一个端基氯原子配位，形成一个四方锥几何构型。桥连氯原子和桥连H₂mbdpz配体连接铜原子以构建延伸的一维链。这些链通过N—H⋯Cl氢键进一步连接，在(011)平面上形成二维层。每对相邻铜原子之间存在一个对称中心。
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