• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

N'-(5-溴-2-羟基-亚苄基)-4-氯苯甲酰肼

N'-(5-Bromo-2-hydroxy-benzyl-idene)-4-chloro-benzohydrazide.

作者信息

Zhou Cong-Shan, Yang Tao

机构信息

College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang, Hunan 414006, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):o751. doi: 10.1107/S160053681000752X.

DOI:10.1107/S160053681000752X
PMID:21580596
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983862/
Abstract

The title Schiff base, C(14)H(10)BrClN(2)O(2), exists in a trans configuration with respect to the C=N bond and the dihedral angle between the two benzene rings is 0.8 (2)°. There is an intra-molecular O-H⋯N hydrogen bond in the mol-ecule, which generates an S(6) loop. In the crystal, inter-molecular N-H⋯O hydrogen bonds link adjacent mol-ecules into extended chains propagating along the c-axis direction.

摘要

席夫碱标题化合物C(14)H(10)BrClN(2)O(2)相对于C=N键呈反式构型，两个苯环之间的二面角为0.8 (2)°。分子内存在O-H⋯N氢键，形成一个S(6)环。在晶体中，分子间N-H⋯O氢键将相邻分子连接成沿c轴方向延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/66f1/2983862/e649d0862c15/e-66-0o751-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/66f1/2983862/38d9d4b3e579/e-66-0o751-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/66f1/2983862/e649d0862c15/e-66-0o751-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/66f1/2983862/38d9d4b3e579/e-66-0o751-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/66f1/2983862/e649d0862c15/e-66-0o751-fig2.jpg

相似文献

1
N'-(5-Bromo-2-hydroxy-benzyl-idene)-4-chloro-benzohydrazide.N'-(5-溴-2-羟基-亚苄基)-4-氯苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):o751. doi: 10.1107/S160053681000752X.
2
N'-(5-Chloro-2-hydroxy-benzyl-idene)-4-hydroxy-benzohydrazide.N'-(5-氯-2-羟基-亚苄基)-4-羟基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 8;65(Pt 5):o975. doi: 10.1107/S160053680901215X.
3
N'-(3-Bromo-5-chloro-2-hydroxy-benzyl-idene)-2-methoxy-benzohydrazide.N'-(3-溴-5-氯-2-羟基-亚苄基)-2-甲氧基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):o851. doi: 10.1107/S1600536809010198.
4
2-Chloro-N'-(2,4-dichloro-benzyl-idene)benzohydrazide.2-氯-N'-(2,4-二氯亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):o752. doi: 10.1107/S1600536810007531.
5
(E)-3-Bromo-N'-(2-chloro-benzyl-idene)benzohydrazide.（E）-3-溴-N'-（2-氯亚苄基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):o1705. doi: 10.1107/S160053680902412X.
6
4-Chloro-N'-(5-chloro-2-hydroxy-benzyl-idene)benzohydrazide.4-氯-N'-(5-氯-2-羟基-亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 16;64(Pt 9):o1758. doi: 10.1107/S1600536808025816.
7
3-Bromo-N'-(3,5-dibromo-2-hydroxy-benzyl-idene)benzohydrazide methanol solvate.3-溴-N'-(3,5-二溴-2-羟基-亚苄基)苯甲酰肼甲醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o688. doi: 10.1107/S1600536809007466.
8
3-Bromo-N'-(2-hydr-oxy-3,5-diiodo-benzyl-idene)benzohydrazide monohydrate.3-溴-N'-(2-羟基-3,5-二碘亚苄基)苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):o905-6. doi: 10.1107/S1600536809010964.
9
4-Chloro-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.4-氯-N'-(2-羟基-4-甲氧基亚苄基)苯甲酰肼甲醇单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o2825. doi: 10.1107/S1600536811039778. Epub 2011 Oct 5.
10
N'-[(E)-1-(5-Bromo-2-hy-droxy-phen-yl)ethyl-idene]-2-chloro-benzohydrazide.N'-[(E)-1-(5-溴-2-羟基苯基)亚乙基]-2-氯苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3365. doi: 10.1107/S1600536811048495. Epub 2011 Nov 19.

引用本文的文献

1
2-Chloro-N'-(2,4-dichloro-benzyl-idene)benzohydrazide.2-氯-N'-(2,4-二氯亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):o752. doi: 10.1107/S1600536810007531.

本文引用的文献

1
(E)-N'-(2-Hydroxy-benzyl-idene)-2-(4-isobutyl-phen-yl)propanohydrazide.（E）-N'-（2-羟基-亚苄基）-2-（4-异丁基苯基）丙酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):o24. doi: 10.1107/S1600536809050971.
2
2-Chloro-N'-(5-hydr-oxy-2-nitro-benzyl-idene)benzohydrazide.2-氯-N'-(5-羟基-2-硝基亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 16;66(Pt 2):o365. doi: 10.1107/S1600536810001303.
3
2-Chloro-N'-(4-nitro-benzyl-idene)benzo-hydrazide.2-氯-N'-(4-硝基-亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):o290. doi: 10.1107/S1600536809055330.
4
N'-[(E)-(4-Bromo-2-thien-yl)methyl-idene]benzohydrazide 0.06-hydrate.N'-[(E)-(4-溴-2-噻吩基)亚甲基]苯甲酰肼0.06水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 19;65(Pt 10):o2501. doi: 10.1107/S1600536809037350.
5
N,N-Bis(2,2-dimethyl-propano-yl)benzene-1,3-dicarbohydrazide.N,N-双(2,2-二甲基丙酰基)苯-1,3-二碳酰肼
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):o175-6. doi: 10.1107/S1600536807063210.
6
Synthesis, spectral characterization, in vitro antibacterial, antifungal and cytotoxic activities of Co(II), Ni(II) and Cu(II) complexes with 1,2,4-triazole Schiff bases.钴（II）、镍（II）和铜（II）与1,2,4-三唑席夫碱配合物的合成、光谱表征、体外抗菌、抗真菌及细胞毒性活性
Eur J Med Chem. 2008 Dec;43(12):2639-49. doi: 10.1016/j.ejmech.2008.02.013. Epub 2008 Feb 29.
7
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.