• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

4-氯-N'-(5-氯-2-羟基-亚苄基)苯甲酰肼

4-Chloro-N'-(5-chloro-2-hydroxy-benzyl-idene)benzohydrazide.

作者信息

Yang De-Suo

机构信息

Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 16;64(Pt 9):o1758. doi: 10.1107/S1600536808025816.

DOI:10.1107/S1600536808025816
PMID:21201740
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960552/
Abstract

The mol-ecule of the title compound, C(14)H(10)Cl(2)N(2)O(2), displays a trans configuration with respect to the C=N double bond and has an intramolecular O-H⋯N hydrogen bond. The dihedral angle between the two benzene rings is 1.4 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the a direction.

摘要

标题化合物C(14)H(10)Cl(2)N(2)O(2)的分子相对于C=N双键呈反式构型，并具有分子内O-H⋯N氢键。两个苯环之间的二面角为1.4 (2)°。在晶体结构中，分子通过分子间N-H⋯O氢键相连，形成沿a方向延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cfed/2960552/223341d0cbc0/e-64-o1758-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cfed/2960552/79ab0aca93ad/e-64-o1758-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cfed/2960552/223341d0cbc0/e-64-o1758-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cfed/2960552/79ab0aca93ad/e-64-o1758-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cfed/2960552/223341d0cbc0/e-64-o1758-fig2.jpg

相似文献

1
4-Chloro-N'-(5-chloro-2-hydroxy-benzyl-idene)benzohydrazide.4-氯-N'-(5-氯-2-羟基-亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 16;64(Pt 9):o1758. doi: 10.1107/S1600536808025816.
2
N'-(3-Bromo-5-chloro-2-hydroxy-benzyl-idene)-2-methoxy-benzohydrazide.N'-(3-溴-5-氯-2-羟基-亚苄基)-2-甲氧基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):o851. doi: 10.1107/S1600536809010198.
3
(E)-4-Chloro-N'-(4-hydroxy-benzyl-idene)-benzohydrazide.（E）-4-氯-N'-（4-羟基-亚苄基）-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 30;64(Pt 9):o1849. doi: 10.1107/S1600536808027013.
4
N'-(5-Chloro-2-hydroxy-benzyl-idene)-4-hydroxy-benzohydrazide.N'-(5-氯-2-羟基-亚苄基)-4-羟基-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 8;65(Pt 5):o975. doi: 10.1107/S160053680901215X.
5
(E)-4-Chloro-N'-(2-chloro-benzyl-idene)benzohydrazide.（E）-4-氯-N'-（2-氯-亚苄基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 9;65(Pt 10):o2384. doi: 10.1107/S1600536809035739.
6
2-Chloro-N'-(2-chloro-benzyl-idene)benzohydrazide.2-氯-N'-(2-氯亚苄基)苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 28;65(Pt 11):o2871. doi: 10.1107/S1600536809043803.
7
N'-(4-Chloro-benzyl-idene)-2-hydroxy-benzohydrazide.N'-(4-氯-亚苄基)-2-羟基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 10;65(Pt 1):o84. doi: 10.1107/S160053680803972X.
8
(E)-4-Chloro-N'-[1-(4-hydroxy-phenyl)-ethylidene]benzohydrazide.（E）-4-氯-N'-[1-（4-羟基苯基）亚乙基]苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 30;64(Pt 9):o1850. doi: 10.1107/S1600536808027001.
9
4-Chloro-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide methanol monosolvate.4-氯-N'-(2-羟基-4-甲氧基亚苄基)苯甲酰肼甲醇单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o2825. doi: 10.1107/S1600536811039778. Epub 2011 Oct 5.
10
N'-(5-Bromo-2-hydroxy-benzyl-idene)-4-chloro-benzohydrazide.N'-(5-溴-2-羟基-亚苄基)-4-氯苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):o751. doi: 10.1107/S160053681000752X.

引用本文的文献

1
3-Hydr-oxy-N'-(5-hydr-oxy-2-nitro-benzyl-idene)-2-naphthohydrazide.
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 4;65(Pt 12):o2978. doi: 10.1107/S1600536809045279.
2
N'-(5-Hydr-oxy-2-nitro-benzyl-idene)-2-methoxy-benzohydrazide.N'-(5-羟基-2-硝基亚苄基)-2-甲氧基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 28;65(Pt 11):o2864. doi: 10.1107/S1600536809043840.
3
(E)-4-Chloro-N'-[1-(4-hydroxy-phenyl)-ethylidene]benzohydrazide.（E）-4-氯-N'-[1-（4-羟基苯基）亚乙基]苯甲酰肼

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Novel copper(II) induced formation of a porphyrinogen derivative: X-ray structural, spectroscopic, and electrochemical studies of porphyrinogen complexes of Cu(II) and Co(III) complex of a trispyrazolyl tripodal ligand.新型铜（II）诱导卟吩原衍生物的形成：三吡唑基三脚架配体的铜（II）和钴（III）配合物的卟吩原配合物的X射线结构、光谱和电化学研究
Inorg Chem. 2002 Nov 4;41(22):5803-9. doi: 10.1021/ic0112185.
3
Synthesis and Characterization of New Chiral Schiff Base Complexes with Diiminobinaphthyl or Diiminocyclohexyl Moieties as Potential Enantioselective Epoxidation Catalysts.
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 30;64(Pt 9):o1850. doi: 10.1107/S1600536808027001.
4
(E)-4-Chloro-N'-(4-hydroxy-benzyl-idene)-benzohydrazide.（E）-4-氯-N'-（4-羟基-亚苄基）-苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 30;64(Pt 9):o1849. doi: 10.1107/S1600536808027013.
具有二亚氨基联萘基或二亚氨基环己基部分的新型手性席夫碱配合物的合成与表征：潜在的对映选择性环氧化催化剂
Inorg Chem. 1996 Jan 17;35(2):387-396. doi: 10.1021/ic950700i.
4
Autoxidation of substituted phenols catalyzed by cobalt Schiff base complexes in supercritical carbon dioxide.
Inorg Chem. 2001 Jul 2;40(14):3336-41. doi: 10.1021/ic001288w.