双[1-(2,6-二氯苄基)-3-甲基吡嗪-1-鎓]双(马来腈二硫醇根合)镍(II)
Bis[1-(2,6-dichloro-benz-yl)-3-methyl-pyrazin-1-ium] bis-(maleonitrile-dithiol-ato)nickelate(II).
作者信息
Yu Shan-Shan, Xian Hua, Tian Zheng-Fang
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 31;64(Pt 11):m1444. doi: 10.1107/S1600536808034776.
Abstract
In the crystal structure of the title compound, (C(12)H(11)Cl(2)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) complex dianion is located on an inversion centre. The Ni(II) atom is coordinated by four S atoms in a square-planar geometry. In the cation, the dihedral angle between the benzene and pyrazine rings is 85.2 (2)°.
摘要
在标题化合物（C₁₂H₁₁Cl₂N₂）₂[Ni（C₄N₂S₂）₂]的晶体结构中，Ni（II）配合物二价阴离子位于一个对称中心上。Ni（II）原子由四个硫原子以平面正方形几何构型配位。在阳离子中，苯环和吡嗪环之间的二面角为85.2 （2）°。
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