链状聚[[(1,10 - 菲咯啉 - κN,N')铜(I)] - μ - 硫氰酸根合 - κN:S - [(1,10 - 菲咯啉 - κN,N')铜(I)] - μ - 氰根合 - κN:C]
catena-Poly[[(1,10-phenanthroline-κN,N')copper(I)]-μ-thiocyanato-κN:S-[(1,10-phenanthroline-κN,N')copper(I)]-μ-cyanido-κN:C].
作者信息
Zhao Jun, Dong Wen-Wen, Li Dong-Sheng, Ke Xi-Jun
机构信息
College of Mechanical and Material Engineering, Functional Materials Research Institue, Three Gorges University, Yichang 443002, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 20;64(Pt 12):m1577. doi: 10.1107/S1600536808037744.
In the title complex, [Cu(2)(CN)(NCS)(C(12)H(8)N(2))(2)], which was synthesized under hydro-thermal conditions, both Cu(I) atoms have a slightly distorted tetra-hedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thio-cyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu-CN-Cu-SCN}(n) chains are formed along [01].
在水热条件下合成的标题配合物[Cu₂(CN)(NCS)(C₁₂H₈N₂)₂]中，两个Cu(I)原子均具有轻微扭曲的四面体几何构型。它们由一个1,10 - 菲咯啉配体的两个N原子、一个桥连硫氰酸根阴离子和一个桥连氰根阴离子配位。在晶体结构中，沿[01]方向形成了无限螺旋状的{Cu - CN - Cu - SCN}ₙ链。
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