吡啶插入铁-硅键：产物Cp*(CO)Fe[η3(C,C,C)-C5H5NSiMe2NPh2]的结构
Insertion of pyridine into an iron-silicon bond: structure of the product Cp*(CO)Fe[eta3(C,C,C)-C5H5NSiMe2NPh2].
作者信息
Iwata Masatoshi, Okazaki Masaaki, Tobita Hiromi
机构信息
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
出版信息
Chem Commun (Camb). 2003 Nov 7(21):2744-5. doi: 10.1039/b308885e.
DOI:10.1039/b308885e
PMID:14649840
Abstract
Heating a toluene solution of Cp*(CO)(C5H5N)FeSiMe2NPh2 led to insertion of pyridine into the iron-silicon bond to form Cp*(CO)Fe[eta3(C,C,C)-C5H5NSiMe2NPh2].
摘要
加热Cp*(CO)(C5H5N)FeSiMe2NPh2的甲苯溶液会导致吡啶插入铁-硅键中，形成Cp*(CO)Fe[η3(C,C,C)-C5H5NSiMe2NPh2]。
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