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三水合三氯化三（2,2'-联吡啶-κN:N'）钴（III）

Tris(2,2'-bipyridine-κN:N')cobalt(III) trichloride tetra-hydrate.

作者信息

Liu Wen, Xu Wei, Lin Jian-Li, Xie Hong-Zhen

机构信息

State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1586. doi: 10.1107/S1600536808038154.

DOI:10.1107/S1600536808038154
PMID:21581186
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959986/
Abstract

The title compound, [Co(C(10)H(8)N(2))(3)]Cl(3)·4H(2)O, contains discrete Co(bpy)(3) cations (bpy is 2,2'-bipyridine), Cl(-) anions and water mol-ecules. The Co(bpy)(3) complex cation exhibits C(2) symmetry with the twofold axis through the central Co atom and bis-ecting one bpy ligand and one of the Cl(-) anions. The four solvent water mol-ecules and the remaining two Cl(-) anions lie on a mirror plane. Hydrogen-bond inter-actions define a two-dimensional layer structure parallel to (100), which consists of seven-membered [Cl(2)(H(2)O)(5)], eight-membered [Cl(4)(H(2)O)(4)] and ten-membered [Cl(2)(H(2)O)(8)] rings.

摘要

标题化合物[Co(C₁₀H₈N₂)₃]Cl₃·4H₂O包含离散的[Co(bpy)₃]³⁺阳离子（bpy为2,2'-联吡啶）、Cl⁻阴离子和水分子。[Co(bpy)₃]³⁺络合阳离子具有C₂对称性，二重轴穿过中心Co原子并平分一个bpy配体和一个Cl⁻阴离子。四个溶剂水分子和其余两个Cl⁻阴离子位于一个镜面上。氢键相互作用定义了一个平行于(100)的二维层状结构，该结构由七元环[Cl₂(H₂O)₅]、八元环[Cl₄(H₂O)₄]和十元环[Cl₂(H₂O)₈]组成。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/b2a01f95903e/e-64-m1586-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/9f14638d1b86/e-64-m1586-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/5bdca77b8c4b/e-64-m1586-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/8a5f3e2dcd47/e-64-m1586-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/b2a01f95903e/e-64-m1586-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/9f14638d1b86/e-64-m1586-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/5bdca77b8c4b/e-64-m1586-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/8a5f3e2dcd47/e-64-m1586-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18ee/2959986/b2a01f95903e/e-64-m1586-fig4.jpg

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