Amini Mostafa M, Hajiashrafi Taraneh, Kharat Ali Nemati, Ng Seik Weng
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 26;64(Pt 12):m1614. doi: 10.1107/S1600536808038567.
In the cyclo-hexa-meric centrosymmetric title compound, [Sn(6)(C(6)H(5))(6)(C(14)H(11)O(2))(6)O(6)], each bridging oxide O atom is connected to three Sn atoms and each carboxyl-ate group bridges a pair of Sn atoms so that the three independent Sn atoms all adopt SnCO(5) distorted octa-hedral geometries, resulting in a drum-shaped Sn(6)O(6) core.
在中心对称的六聚体标题化合物[Sn₆(C₆H₅)₆(C₁₄H₁₁O₂)₆O₆]中,每个桥连的氧原子与三个锡原子相连,每个羧酸根基团桥连一对锡原子,使得三个独立的锡原子均采用SnCO₅扭曲八面体几何构型,从而形成一个鼓形的Sn₆O₆核。