双{μ-2-[(N,N-二异丙基-氨基硫甲酰基)硫烷基]乙酸根合-κO:O'}双(双(4-氯苄基){2-[(N,N-二异丙基-氨基硫甲酰基)硫烷基]乙酸根合-κO,O'}锡(IV))
Bis{μ-2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-κO:O'}bis-(bis-(4-chloro-benz-yl){2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-κO,O'}tin(IV)).
作者信息
Keng Thy Chun, Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m661. doi: 10.1107/S1600536811015716. Epub 2011 May 7.
Abstract
The dinuclear title complex, [Sn(2)(C(7)H(6)Cl)(4)(C(9)H(16)NO(2)S(2))(4)], lies on a center of inversion. The Sn(IV) atoms are chelated by one of the two carboxyl-ate ions; the other carboxyl-ate ion bridges two metal atoms. The geometry of the six-coordinate Sn(IV) atom is a distorted trans-C(2)SnO(4) octa-hedron [C-Sn-C = 155.32 (8)°].
摘要
双核标题配合物[Sn₂(C₇H₆Cl)₄(C₉H₁₆NO₂S₂)₄]位于一个对称中心上。两个羧酸根离子中的一个螯合Sn(IV)原子；另一个羧酸根离子桥连两个金属原子。六配位Sn(IV)原子的几何构型为扭曲的反式-C₂SnO₄八面体[C-Sn-C = 155.32 (8)°]。
相似文献
1
Bis{μ-2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-κO:O'}bis-(bis-(4-chloro-benz-yl){2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-κO,O'}tin(IV)).双{μ-2-[(N,N-二异丙基-氨基硫甲酰基)硫烷基]乙酸根合-κO:O'}双(双(4-氯苄基){2-[(N,N-二异丙基-氨基硫甲酰基)硫烷基]乙酸根合-κO,O'}锡(IV))
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m661. doi: 10.1107/S1600536811015716. Epub 2011 May 7.
2
catena-Poly[[triphenyl-tin(IV)]-μ-2-[(3,5-di-tert-butyl-4-hydroxy-benz-yl)sulfan-yl]acetato-κO:O'].链状聚[[三苯基锡(IV)]-μ-2-[(3,5-二叔丁基-4-羟基苄基)硫烷基]乙酸根-κO:O']
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m808. doi: 10.1107/S1600536809023150.
3
μ-1,4-Bis(diphenyl-phosphino-yl)butane-κO:O']bis-[cyclo-pentyl-diphen-yl(trifluoro-acetato-κO)tin(IV).μ-1,4-双（二苯基膦基）丁烷-κO:O']双- [环戊基-二苯基（三氟乙酸根-κO）锡（IV）]
Acta Crystallogr Sect E Struct Rep Online. 2008 May 10;64(Pt 6):m790. doi: 10.1107/S1600536808013202.
4
catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio-ylsulfan-yl]acetato-κO:O'].链状聚[[三（4-氟苄基）锡（IV）]-μ-2-[(哌啶-1-基）碳硫酰硫基]乙酸根-κO:O']
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 21;66(Pt 8):m978. doi: 10.1107/S1600536810028321.
5
Bis(μ-quinoline-2-carboxyl-ato)-κN,O:O;κO:N,O-bis-[(acetato-κO,O')(methanol-κO)lead(II)].双（μ-喹啉-2-羧酸根）-κN,O:O;κO:N,O-双-[(乙酸根-κO,O')(甲醇-κO)铅(II)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 17;66(Pt 8):m963. doi: 10.1107/S1600536810027777.
6
catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]{μ-[(N,N-diisopropylcar-bamo-thioyl)sulfanyl]acetato-κO:O'}].链状聚[[三（4-氟苄基）锡（IV）]{μ-[(N,N-二异丙基氨基甲酰硫基）硫代]乙酸根-κO:O'}]
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 20;66(Pt 3):m314. doi: 10.1107/S1600536810005933.
7
Bis(μ-5-chloro-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[(acetato-κO,O')lead(II)].双（μ-5-氯喹啉-8-醇根）-κN，O：O；κO：N，O-双-[(乙酸根-κO，O')铅(II)]
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 11;65(Pt 3):m261. doi: 10.1107/S1600536809003559.
8
Poly[bis-(μ(4)-acetato-κO:O:O':O')bis-(μ(3)-acetato-κO:O:O)(μ(2)-acetato-κO:O')(μ(2)-acetic acid-κO:O')di-μ-aqua-copper(II)tris-odium].聚[双（μ(4)-乙酸根-κO:O:O':O'）双（μ(3)-乙酸根-κO:O:O）（μ(2)-乙酸根-κO:O'）（μ(2)-乙酸-κO:O'）双-μ-水合铜（II）三钠]
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1244. doi: 10.1107/S1600536810035683.
9
Bis{2-[bis-(2-hy-droxy-eth-yl)amino]-acetato-κO,N,O'}zinc(II).双{2-[双-(2-羟乙基)氨基]-乙酸根合-κO,N,O'}锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 30;66(Pt 11):m1485. doi: 10.1107/S1600536810043217.
10
Tricyclo-hex-yl{2-[(3,5-di-tert-butyl-4-hy-droxy-benz-yl)sulfan-yl]acetato-κO}tin(IV).三环己基{2-[(3,5-二叔丁基-4-羟基苄基)硫烷基]乙酸根合-κO}锡(IV)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m792. doi: 10.1107/S1600536810021884.
本文引用的文献
1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
Zotero 插件