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双{μ-2-[(N,N-二异丙基-氨基硫甲酰基)硫烷基]乙酸根合-κO:O'}双(双(4-氯苄基){2-[(N,N-二异丙基-氨基硫甲酰基)硫烷基]乙酸根合-κO,O'}锡(IV))

Bis{μ-2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-κO:O'}bis-(bis-(4-chloro-benz-yl){2-[(N,N-diisopropyl-carbamothio-yl)sulfan-yl]acetato-κO,O'}tin(IV)).

作者信息

Keng Thy Chun, Lo Kong Mun, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m661. doi: 10.1107/S1600536811015716. Epub 2011 May 7.

DOI:10.1107/S1600536811015716
PMID:21754573
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120461/
Abstract

The dinuclear title complex, [Sn(2)(C(7)H(6)Cl)(4)(C(9)H(16)NO(2)S(2))(4)], lies on a center of inversion. The Sn(IV) atoms are chelated by one of the two carboxyl-ate ions; the other carboxyl-ate ion bridges two metal atoms. The geometry of the six-coordinate Sn(IV) atom is a distorted trans-C(2)SnO(4) octa-hedron [C-Sn-C = 155.32 (8)°].

摘要

双核标题配合物[Sn₂(C₇H₆Cl)₄(C₉H₁₆NO₂S₂)₄]位于一个对称中心上。两个羧酸根离子中的一个螯合Sn(IV)原子；另一个羧酸根离子桥连两个金属原子。六配位Sn(IV)原子的几何构型为扭曲的反式-C₂SnO₄八面体[C-Sn-C = 155.32 (8)°]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4121/3120461/8aafb30eacfe/e-67-0m661-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4121/3120461/8aafb30eacfe/e-67-0m661-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4121/3120461/8aafb30eacfe/e-67-0m661-fig1.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
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