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N-丁基-4-氯苯甲酰胺

N-Butyl-4-chloro-benzamide.

作者信息

Saeed Aamer, Khera Rasheed Ahmad, Abbas Naeem, Simpson Jim, Stanley Roderick G

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 13;64(Pt 12):o2322-3. doi: 10.1107/S1600536808036313.

DOI:10.1107/S1600536808036313
PMID:21581298
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960128/
Abstract

In the title benzamide derivative, C(11)H(14)ClNO, the chloro-benzene and butyl-amine groups are each planar, with mean deviations from the planes of 0.013 and 0.030 Å, respectively, and a dihedral angle of 2.54 (9)° between the two planes. In the crystal structure, N-H⋯O hydrogen bonds link mol-ecules in rows along a. Short inter-molecular Cl⋯Cl inter-actions [3.4225 (5) Å] link these rows into sheets in the ac plane. Additional weak C-H⋯O and C-H⋯π inter-actions generate a three-dimensional network.

摘要

在标题为苯甲酰胺衍生物C(11)H(14)ClNO中，氯苯和丁胺基团各自呈平面状，与平面的平均偏差分别为0.013 Å和0.030 Å，两个平面之间的二面角为2.54 (9)°。在晶体结构中，N—H⋯O氢键沿a轴将分子连接成排。短的分子间Cl⋯Cl相互作用[3.4225 (5) Å]将这些排连接成ac平面内的片层。额外的弱C—H⋯O和C—H⋯π相互作用形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f99/2960128/e2820e18c286/e-64-o2322-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f99/2960128/659bd7d1a5d5/e-64-o2322-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f99/2960128/5055230bad4b/e-64-o2322-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f99/2960128/e2820e18c286/e-64-o2322-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f99/2960128/659bd7d1a5d5/e-64-o2322-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f99/2960128/5055230bad4b/e-64-o2322-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f99/2960128/e2820e18c286/e-64-o2322-fig3.jpg

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