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2,4-双(2-溴苯基)-3-氮杂双环-[3.3.1]壬烷-9-酮

2,4-Bis(2-bromo-phen-yl)-3-aza-bicyclo-[3.3.1]nonan-9-one.

作者信息

Parthiban P, Ramkumar V, Kim Min Sung, Son Se Mo, Jeong Yeon Tae

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 20;64(Pt 12):o2385. doi: 10.1107/S1600536808037501.

DOI:10.1107/S1600536808037501
PMID:21581356
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959882/
Abstract

In the mol-ecular structure of the title compound, C(20)H(19)Br(2)NO, the fused six-membered heterocyclic and cyclo-hexane rings adopt a twin-chair conformation with equatorial orientations of all the substituents. Both the ortho-bromo substituents of the benzene rings are oriented towards the carbonyl group; the dihedral angle between the ring planes is 29.13 (3)°. In the crystal structure, the N-H group does not participate in any hydrogen bonds.

摘要

在标题化合物C(20)H(19)Br(2)NO的分子结构中，稠合的六元杂环和环己烷环采取双椅式构象，所有取代基均处于平伏取向。苯环上的两个邻位溴取代基均朝向羰基；环平面之间的二面角为29.13 (3)°。在晶体结构中，N-H基团不参与任何氢键作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/86a7/2959882/188d2ed162bf/e-64-o2385-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/86a7/2959882/188d2ed162bf/e-64-o2385-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/86a7/2959882/188d2ed162bf/e-64-o2385-fig1.jpg

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