二氯{[2-(二苯基膦基)苯基-亚氨基-甲基]二茂铁-κN,P}钯(II) 二氯甲烷半溶剂合物
Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-κN,P}palladium(II) dichloro-methane hemi-solvate.
作者信息
Liu Huanyu, Shen Dongsheng
机构信息
College of Pharmacy, Guangdong Pharmaceutical University, Guangzhou 510006, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 3;65(Pt 1):m8. doi: 10.1107/S1600536808039949.
There are two independent Pd(II) complex mol-ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol-ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene ligand and two chloride anions.
标题化合物[PdCl₂{Fe(C₅H₅)(C₂₄H₁₉NP)}]·0.5CH₂Cl₂的不对称单元中有两个独立的Pd(II)配合物分子。一个配合物分子的一个二茂铁基环在两个位置上无序，每个组分的占有率为一半。两个Pd(II)阳离子均采用扭曲的平面正方形配位几何构型，配体为双齿的[2-(二苯基膦基)苯基-亚氨基-甲基]二茂铁和两个氯离子。
Zotero 插件