二氯{[2-(二苯基膦基)苯基-亚氨基-甲基]二茂铁-κN,P}铂(II) 二氯甲烷半溶剂化物
Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-κN,P}platinum(II) dichloro-methane hemisolvate.
作者信息
Xie Yu, Wei Ya, Hu Jin-Gang, Zhao Jin-Sheng, Jiang Feng-Xing
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m138. doi: 10.1107/S1600536808043493.
Abstract
In the title compound, [FePt(C(5)H(5))(C(24)H(19)NP)Cl(2)]·0.5CH(2)Cl(2), the Pt(II) atom adopts a distorted square-planar geometry defined by one P atom and one N atom from the bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferro-cene ligand and two Cl atoms. Two disordered dichloro-methane solvent mol-ecules are each 0.25-occupied on a twofold rotation axis.
摘要
在标题化合物[FePt(C₅H₅)(C₂₄H₁₉NP)Cl₂]·0.5CH₂Cl₂中，Pt(II)原子采用由双齿[2-(二苯基膦基)苯基亚氨基甲基]二茂铁配体中的一个P原子、一个N原子以及两个Cl原子所定义的扭曲平面正方形几何构型。两个无序的二氯甲烷溶剂分子在一个二重旋转轴上各占据0.25的占有率。
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