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3-溴-N'-(3,5-二氯-2-羟基-亚苄基)苯甲酰肼

3-Bromo-N'-(3,5-dichloro-2-hydroxy-benzyl-idene)benzohydrazide.

作者信息

Zhu Chuan-Gao, Wei Yi-Jun, Zhu Qi-Yong

机构信息

Department of Chemistry, Huainan Normal College, Huainan 232001, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 10;65(Pt 1):o85. doi: 10.1107/S1600536808041378.

DOI:10.1107/S1600536808041378
PMID:21581723
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2967993/
Abstract

The title compound, C(14)H(9)BrCl(2)N(2)O(2), was prepared by the reaction of 3,5-dichloro-2-hydroxy-benzaldehyde and 3-bromo-benzohydrazide in methanol. The dihedral angle between the two benzene rings is 13.0 (2)°. An intra-molecular O-H⋯N hydrogen bond is observed. The mol-ecules are linked into chains along the c axis by inter-molecular N-H⋯O hydrogen bonds.

摘要

标题化合物C(14)H(9)BrCl(2)N(2)O(2)是由3,5-二氯-2-羟基苯甲醛与3-溴苯甲酰肼在甲醇中反应制备的。两个苯环之间的二面角为13.0 (2)°。观察到分子内存在O-H⋯N氢键。分子通过分子间N-H⋯O氢键沿c轴连接成链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4799/2967993/93acc80e88f9/e-65-00o85-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4799/2967993/61b085407f31/e-65-00o85-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4799/2967993/93acc80e88f9/e-65-00o85-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4799/2967993/61b085407f31/e-65-00o85-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4799/2967993/93acc80e88f9/e-65-00o85-fig2.jpg

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本文引用的文献

1
N'-(3,5-Di-tert-butyl-4-hydroxy-benzyl-idene)-2-hydroxy-benzohydrazide methanol solvate.N'-(3,5-二叔丁基-4-羟基-亚苄基)-2-羟基苯甲酰肼甲醇溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 9;64(Pt 8):o1452. doi: 10.1107/S1600536808020746.
2
N'-(4-Hydroxy-benzyl-idene)-4-meth-oxybenzohydrazide.N'-(4-羟基-亚苄基)-4-甲氧基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1682. doi: 10.1107/S160053680802360X.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.