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N'-(5-溴-2-甲氧基-亚苄基)-4-羟基-苯甲酰肼甲醇溶剂合物

N'-(5-Bromo-2-methoxy-benzyl-idene)-4-hydroxy-benzohydrazide methanol solvate.

作者信息

Lin Xue-Song, Sang Ya-Li

机构信息

Department of Chemistry, Chifeng University, Chifeng 024001, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):o1650. doi: 10.1107/S1600536809022983.

DOI:10.1107/S1600536809022983
PMID:21582914
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969367/
Abstract

In the title hydrazone compound, C(15)H(13)BrN(2)O(3)·CH(3)OH, the methanol solvate is linked to the benzohydrazide molecule through O-H⋯N and O-H⋯O hydrogen bonds. The benzohydrazide mol-ecule adopts an E configuration about the C=N double bond. The mol-ecule is twisted, with a dihedral angle between the two substituted benzene rings of 35.7 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O and O-H⋯O hydrogen bonds, forming layers parallel to the ac plane.

摘要

在腙化合物C(15)H(13)BrN(2)O(3)·CH(3)OH中，甲醇溶剂化物通过O-H⋯N和O-H⋯O氢键与苯甲酰肼分子相连。苯甲酰肼分子围绕C=N双键呈E构型。该分子呈扭曲状，两个取代苯环之间的二面角为35.7 (2)°。在晶体结构中，分子通过分子间N-H⋯O和O-H⋯O氢键相连，形成平行于ac平面的层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1bed/2969367/90792f533779/e-65-o1650-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1bed/2969367/4094fb325427/e-65-o1650-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1bed/2969367/90792f533779/e-65-o1650-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1bed/2969367/4094fb325427/e-65-o1650-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1bed/2969367/90792f533779/e-65-o1650-fig2.jpg

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