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链状聚[二乙基(2-羟乙基)铵[[四-μ-乙酸根-κO:O'-二铜(II)(铜-铜)]-μ-乙酸根-κO:O']二氯甲烷溶剂合物]

catena-Poly[dieth-yl(2-hydroxy-ethyl)-ammonium [[tetra-μ-acetato-κO:O'-dicuprate(II)(Cu-Cu)]-μ-acetato-κO:O'] dichloro-methane solvate].

作者信息

Shahid Muhammad, Mazhar Muhammad, O'Brien Paul, Afzaal Mohammad, Raftery James

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m163-4. doi: 10.1107/S1600536808044048.

DOI:10.1107/S1600536808044048
PMID:21581773
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968312/
Abstract

The title compound, {(C(6)H(16)NO)[Cu(2)(CH(3)COO)(5)]·CH(2)Cl(2)}(n), consists of acetate-bridged Cu(2)(CH(3)COO)(4) units that are connected via another acetate anion at each terminus to form infinite anionic {Cu(2)(CH(3)COO)(4)}(CH(3)COO) chains along [100]. The connecting acetate is hydrogen bonded to the dieth-yl(2-hydroxy-ethyl)ammonium cation, and the dichloro-methane solvent mol-ecule fills the remaining voids in the structure. The O-Cu-Cu angles along the polymeric chain are nearly linear [175.49 (5)°], but individual O-Cu-Cu-O units along the chain are bent and rotated against each other at the bridging acetate ion. Translation of each Cu(2)(CH(3)COO)(4) unit along the chain, represented by the least-squares plane of the two copper ions along with four of the acetate O atoms, rotated these units by 35.16 (3)°.

摘要

标题化合物{(C₆H₁₆NO)[Cu₂(CH₃COO)₅]·CH₂Cl₂}ₙ由乙酸根桥连的Cu₂(CH₃COO)₄单元组成，这些单元在每个末端通过另一个乙酸根阴离子相连，沿着[100]方向形成无限的阴离子[{Cu₂(CH₃COO)₄}(CH₃COO)]ₙ链。连接的乙酸根与二乙基(2-羟乙基)铵阳离子形成氢键，二氯甲烷溶剂分子填充结构中的其余空隙。沿着聚合物链的O-Cu-Cu角接近线性[175.49(5)°]，但沿着链的单个O-Cu-Cu-O单元在桥连乙酸根离子处相互弯曲和旋转。每个Cu₂(CH₃COO)₄单元沿着链的平移，由两个铜离子的最小二乘平面以及四个乙酸根O原子表示，使这些单元旋转了35.16(3)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdf7/2968312/033044cdae96/e-65-0m163-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdf7/2968312/211f4f69d6ef/e-65-0m163-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdf7/2968312/71b2a14105ad/e-65-0m163-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdf7/2968312/033044cdae96/e-65-0m163-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdf7/2968312/211f4f69d6ef/e-65-0m163-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdf7/2968312/71b2a14105ad/e-65-0m163-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdf7/2968312/033044cdae96/e-65-0m163-fig3.jpg

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catena-Poly[[[tetra-kis-(4-methyl-pyridine-κN)copper(II)]-μ-sulfato-κO:O'] 4.393-hydrate].
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