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链状聚[三乙铵[[四-μ-乙酸根-κ(8)O:O'-二铜(II)]-μ-乙酸根-κ(2)O:O']四氢呋喃单溶剂合物]

catena-Poly[triethyl-ammonium [[tetra-μ-acetato-κ(8)O:O'-dicuprate(II)]-μ-acetato-κ(2)O:O'] tetra-hydro-furan monosolvate].

作者信息

Bugenhagen Bernhard E C, Prosenc Marc H

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1142. doi: 10.1107/S1600536812033405. Epub 2012 Aug 1.

DOI:10.1107/S1600536812033405
PMID:22969445
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435572/
Abstract

In the title compound, {[(C(2)H(5))(3)NH][Cu(2)(CH(3)COO)(5)]·C(4)H(8)O}(n), the two different Cu(II) atoms are coordinated in a pseudo-square-pyramidal environment by five O atoms from the acetate ligands. Neighbouring pairs of Cu(II) atoms are linked by four basally coordinating bridging acetate ligands as in the crystal structure of copper acetate monohydrate. The fifth, apically coordinating ligand links two of the dicopper tetra-acetate paddlewheel-units together, thus building a linear coordination polymer which extends along [10-1]. Each apical acetate ligand is linked by an N-H⋯O hydrogen bond to a triethyl-ammonium cation. Weak C-H⋯O hydrogen bonding interactions also occur.

摘要

在标题化合物{[(C₂H₅)₃NH][Cu₂(CH₃COO)₅]·C₄H₈O}ₙ中，两个不同的Cu(II)原子在一个准四方锥环境中被来自乙酸根配体的五个O原子配位。相邻的Cu(II)原子对通过四个位于底面配位的桥连乙酸根配体相连，如同在一水合乙酸铜的晶体结构中那样。第五个，位于顶端配位的配体将两个二铜四乙酸桨轮单元连接在一起，从而形成一个沿[10 - 1]方向延伸的线性配位聚合物。每个顶端乙酸根配体通过一个N - H⋯O氢键与一个三乙铵阳离子相连。还存在弱的C - H⋯O氢键相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/168d/3435572/37f84209a434/e-68-m1142-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/168d/3435572/58dd6b6d8467/e-68-m1142-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/168d/3435572/01ecde563d18/e-68-m1142-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/168d/3435572/37f84209a434/e-68-m1142-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/168d/3435572/58dd6b6d8467/e-68-m1142-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/168d/3435572/01ecde563d18/e-68-m1142-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/168d/3435572/37f84209a434/e-68-m1142-fig3.jpg

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