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（3,5,7-三溴-氧代环庚三烯酚酮根合-κO,O'）三（三苯基膦-κP）银（I）

(3,5,7-Tribromo-tropolonato-κO,O')tris-(triphenyl-phosphine-κP)silver(I).

作者信息

Steyl G, Hill T N

机构信息

Department of Chemistry, University of the Free State, Bloemfontein 9300, South Africa.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 14;65(Pt 2):m191. doi: 10.1107/S1600536809000890.

DOI:10.1107/S1600536809000890
PMID:21581792
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968179/
Abstract

The title compound, [Ag(C(7)H(2)Br(3)O(2))(C(18)H(15)P)(3)], a silver(I) derivative of 3,5,7-tribromo-tropolone, has three triphenyl-phosphine ligands coordinated to the silver centre, whereas the 3,5,7-tribromo-tropolonate anion coordinates as a bidentate ligand. The compound is an example of a five-coordinate silver complex containing a bidentate ligand.

摘要

标题化合物[Ag(C₇H₂Br₃O₂)(C₁₈H₁₅P)₃]是3,5,7-三溴环庚三酮的一种银（I）衍生物，有三个三苯基膦配体与银中心配位，而3,5,7-三溴环庚三酮酸根阴离子作为双齿配体配位。该化合物是含双齿配体的五配位银配合物的一个实例。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cbd/2968179/acecc5328fda/e-65-0m191-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cbd/2968179/acecc5328fda/e-65-0m191-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4cbd/2968179/acecc5328fda/e-65-0m191-fig1.jpg

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本文引用的文献

1
Bis(triphenyl-phosphine-κP)(tropolonato-κO,O')silver(I) dichloro-methane solvate.双（三苯基膦-κP）（氧代环庚三烯酚酮-κO，O'）合银（I）二氯甲烷溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 28;65(Pt 2):m233. doi: 10.1107/S1600536809002785.
2
Dicarbon-yl[2-hydr-oxy-3,5,7-tris-(mor-pho-linomethyl)cyclo-hepta-2,4,6-trien-onato(1-)-κO,O]rhodium(I).二羰基[2-羟基-3,5,7-三（吗啉代甲基）环庚-2,4,6-三烯酮酸根合（1-）-κO,O]铑（I）
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 20;64(Pt 12):m1580-1. doi: 10.1107/S160053680803780X.
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A short history of SHELX.
SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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Rhodium hydride formation in the presence of a bulky monophosphite ligand: a spectroscopic and solid-state investigation.在大位阻单亚磷酸酯配体存在下氢化铑的形成：光谱学和固态研究
Dalton Trans. 2005 Mar 21(6):1108-16. doi: 10.1039/b416917d. Epub 2005 Feb 17.