（3,5,7-三溴-氧代环庚三烯酚酮根合-κO,O'）三（三苯基膦-κP）银（I）
(3,5,7-Tribromo-tropolonato-κO,O')tris-(triphenyl-phosphine-κP)silver(I).
作者信息
Steyl G, Hill T N
机构信息
Department of Chemistry, University of the Free State, Bloemfontein 9300, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 14;65(Pt 2):m191. doi: 10.1107/S1600536809000890.
Abstract
The title compound, [Ag(C(7)H(2)Br(3)O(2))(C(18)H(15)P)(3)], a silver(I) derivative of 3,5,7-tribromo-tropolone, has three triphenyl-phosphine ligands coordinated to the silver centre, whereas the 3,5,7-tribromo-tropolonate anion coordinates as a bidentate ligand. The compound is an example of a five-coordinate silver complex containing a bidentate ligand.
摘要
标题化合物[Ag(C₇H₂Br₃O₂)(C₁₈H₁₅P)₃]是3,5,7-三溴环庚三酮的一种银（I）衍生物，有三个三苯基膦配体与银中心配位，而3,5,7-三溴环庚三酮酸根阴离子作为双齿配体配位。该化合物是含双齿配体的五配位银配合物的一个实例。
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