双[三（4-氟苯基）膦-κP]（氧杂环庚三烯酮-κO，O'）铜（I）
Bis[tris-(4-fluoro-phen-yl)phosphine-κP](tropolonato-κO,O')copper(I).
作者信息
Steyl Gideon
机构信息
Department of Chemistry, University of the Free State, Bloemfontein 9300, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):m448. doi: 10.1107/S1600536809010630.
The title compound, [Cu(C(7)H(5)O(2))(C(18)H(12)F(3)P)(2)], a copper(I) tris-(4-fluoro-phen-yl)phosphine tropolonate derivative, is the first tropolonate complex with fluorinated aryl-phosphine ligands. The Cu(I) atom has a distorted tetra-hedral coordination; the most important geometrical parameters of the mol-ecule are: Cu-P = 2.2377 (10) and 2.2335 (15) Å, Cu-O = 2.084 (2) and 2.082 (2) Å, O-Cu-O = 77.72 (10)°, P-Cu-P = 128.82 (4)° and O-C-C-O = -2.1 (5)°.
标题化合物[Cu(C₇H₅O₂)(C₁₈H₁₂F₃P)₂]，一种铜（I）三（4-氟苯基）膦基环庚三烯酚酮衍生物，是首个含氟芳基膦配体的环庚三烯酚酮配合物。Cu（I）原子具有扭曲的四面体配位；该分子最重要的几何参数为：Cu-P = 2.2377 (10) 和2.2335 (15) Å，Cu-O = 2.084 (2) 和2.082 (2) Å，O-Cu-O = 77.72 (10)°，P-Cu-P = 128.82 (4)° 以及O-C-C-O = -2.1 (5)°。
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