Steyl Gideon, Hill Tania N
Department of Chemistry, University of the Free State, Bloemfontein 9300, South Africa.
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 28;65(Pt 2):m233. doi: 10.1107/S1600536809002785.
The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra-hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl-phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.
标题化合物[Ag(C₇H₅O₂)(C₁₈H₁₅P)₂]·CH₂Cl₂以围绕Ag(I)原子的扭曲四面体几何构型结晶,该构型由来自一个托酚酮配体的两个O原子和来自两个三苯基膦配体的两个P原子确定。它是一种新型托酚酮衍生物的实例,尚未通过固态方法进行表征。